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学者姓名：张健
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摘要 ：
Three new water-stable In(III)-based metalorganic frameworks, namely, [In-3(TTTA)(2)(OH)(3)(H2O)]center dot(DMA)3 (BUT-70, DMA = N,N-dimethylacetamide), [In-3(TTTA)(2)(CH3O)(3)] (BUT-70A), and [In-3(TTTA)(2)(OH)(3)] (BUT-70B), with rod-shaped secondary building units (SBUs) and an new acrylate-based ligand, (2E,2'E,2 '' E)-3,3',3 ''-(2,4,6-trimethylbenzene-1,3,5-triyl)-triacrylate (TTTA(3)) were obtained and structurally characterized. BUT-70A and -70B were generated in a single-crystal to single-crystal transformation fashion from BUT-70 through guest exchange followed by their removal. The solvents used for guest exchange were methanol and dichloromethane, respectively. Single-crystal structure analyses show that the guest exchange and removal process is accompanied by the substitution of coordinated water molecules of In(III) centers with uncoordinated carboxylate O atoms of TTTA(3) ligands. Moreover, hydroxyl groups bridging two In(III) centers are also replaced by methoxyl groups in the transformation from BUT-70 to -70A. Overall, three metalorganic frameworks (MOFs) are constructed by infinite chains consisting of corner-sharing InO4(OR)(2) (R = H or Me) octahedral entities, which are interconnected by TTTA(3) ligands to form three-dimensional frameworks. Unlike most reported MOFs with infinite chains as SBUs, such as well-known MIL-53 and M-MOF-74, which have one-dimensional channels along the chain direction, the BUT-70 series contain two-dimensional intersecting channels. The BrunauerEmmettTeller surface area and pore volume of BUT-70A were estimated to be 460 m(2) g(1) and 0.18 cm(3) g(1), respectively, which are obviously lower than those of BUT-70B (695 m(2) g(1) and 0.29 cm(3) g(1)). Gas adsorption experiments demonstrated that BUT-70A and -70B are able to selectively adsorb C2H2 over CO2 and CH4. At 1 atm and 298 K, BUT-70A uptakes 3.1 mmol g(1) C2H2, which is 3.6 times that of the CO2 uptake and 7.2 times that of the CH4 uptake. Compared with BUT-70A, BUT-70B presents an even higher C2H2 uptake of 3.9 mmol g1 at the same conditions, but slightly lower Ideal Adsorbed Solution Theory C2H2/CO2 and C2H2/CH4 selectivities.
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| GB/T 7714 | Guo, Zhen-Ji , Yu, Jiamei , Zhang, Yong-Zheng et al. Water-Stable In(III)-Based Metal-Organic Frameworks with Rod-Shaped Secondary Building Units: Single-Crystal to Single-Crystal Transformation and Selective Sorption of C2H2 over CO2 and CH4 [J]. | INORGANIC CHEMISTRY , 2017 , 56 (4) : 2188-2197 . |
| MLA | Guo, Zhen-Ji et al. "Water-Stable In(III)-Based Metal-Organic Frameworks with Rod-Shaped Secondary Building Units: Single-Crystal to Single-Crystal Transformation and Selective Sorption of C2H2 over CO2 and CH4" . | INORGANIC CHEMISTRY 56 . 4 (2017) : 2188-2197 . |
| APA | Guo, Zhen-Ji , Yu, Jiamei , Zhang, Yong-Zheng , Zhang, Jian , Chen, Ya , Wu, Yufeng et al. Water-Stable In(III)-Based Metal-Organic Frameworks with Rod-Shaped Secondary Building Units: Single-Crystal to Single-Crystal Transformation and Selective Sorption of C2H2 over CO2 and CH4 . | INORGANIC CHEMISTRY , 2017 , 56 (4) , 2188-2197 . |
| 导入链接 | NoteExpress RIS BibTex |
摘要 ：
Antibiotics and organic explosives are among the main organic pollutants in wastewater; their detection and removal are quite important but challenging. As a new class of-porous materials, Metal organic frameworks (MOPs) are considered as a promising platform for the sensing and adsorption applications. In this work, guided by a topological design approach, two stable isostructural Zr(IV)-based MOFs, Zr6O4(OH)(8)(H2O)(4)(CTTA)(8/3) (BUT-12, H(3)CTTA = 5'-(4-carboxyphenyl)-2',4',6'-trimethyl-[1,1':3',1 ''-terphenyl]-4,4 ''-dicarboxylic acid) and Zr6O4(OH)(8)(H2O)(4)(TTNA)(8/3) (BUT-13, H(3)TTNA = 6,6',6 ''-(2,4,6-trimethylbenzene-1,3,5-triyl)tris(2-naphthoic acid)) with the the-a topological structure constructed by D-4h 8-connected Zr-6 clusters and D-3h 3-connected linkers were designed and synthesized. The two MOFs are highly porous with the Brunauer-Emmett-Teller surface area of 3387 and 3948 m(2) g(-1), respectively. Particularly, BUT-13 features one-of the most porous water-stable MOFs reported so far. Interestingly, these MOFs, represent excellent fluorescent properties, which can be efficiently quenched by trace amounts of nitrofurazone (NZF) and nitrofurantoin (NFT) antibiotics as well as 2,4,6: trinitrophenol (TNP) and 4-nitrophenol (4-NP) organic explosives in water solution. They are responsive to NZF and TNP at parts per billion (ppb) levels, which are among the best performing luminescent MOP-based sensing materials. Simultaneously, both MOFs also display high adsorption abilities toward these organic molecules. It was demonstrated that the adsorption plays an important role in the preconcentration of analytes, which can further increase the fluorescent quenching efficiency. These results indicate that BUT-12 and -13 are favorable materials for the simultaneous selective detection and removal of specific antibiotics and organic explosives from water, being potentially useful in monitoring water quality and treating wastewater.
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| GB/T 7714 | Wang, Bin , Lv, Xiu-Liang , Feng, Dawei et al. Highly Stable Zr(IV)-Based Metal-Organic Frameworks for the Detection and Removal of Antibiotics and Organic Explosives in Water [J]. | JOURNAL OF THE AMERICAN CHEMICAL SOCIETY , 2016 , 138 (19) : 6204-6216 . |
| MLA | Wang, Bin et al. "Highly Stable Zr(IV)-Based Metal-Organic Frameworks for the Detection and Removal of Antibiotics and Organic Explosives in Water" . | JOURNAL OF THE AMERICAN CHEMICAL SOCIETY 138 . 19 (2016) : 6204-6216 . |
| APA | Wang, Bin , Lv, Xiu-Liang , Feng, Dawei , Xie, Lin-Hua , Zhang, Jian , Li, Ming et al. Highly Stable Zr(IV)-Based Metal-Organic Frameworks for the Detection and Removal of Antibiotics and Organic Explosives in Water . | JOURNAL OF THE AMERICAN CHEMICAL SOCIETY , 2016 , 138 (19) , 6204-6216 . |
| 导入链接 | NoteExpress RIS BibTex |
摘要 ：
Through ligand modification, we have replaced the central benzene ring of H2TDBA ([1,1': 3', 1.-terphenyl]-4,4.-dicarboxylicacid) with the pyridine structurally related ligand H2PDDA (4,4'-(pyridine-2,6-diyl) dibenzoic acid), which makes the central pyridine ring of H2PDDA more coplanar with two benzene rings on both sides of the ligand. The modification results in a dramatically different linkage configuration, thereby allowing structural changes to the metal-organic frameworks (MOFs). Two 2-D MOFs, [Cu(TDBA)(DMA)2].H2O (BUT-221, DMA = N,N-dimethylacetamide), and [Cu 3 (PDDA) 3 (DMA) 2 (H2O)].5H2O (BUT-223) have been synthesized through reactions of two ditopic carboxylate ligands with Cu(NO3)2.3H2O under solvothermal conditions, and characterized by single-crystal X-ray diffraction, powder X-ray diffraction, thermogravimetric analysis and infrared spectroscopy. Topological analysis shows that BUT-221 is a twofold parallel interpenetrating 44 2-D network with a skl topology, while BUT-223 is a 2-D network with a kgm topology.
关键词 ：
crystal structure crystal structure ligand modification ligand modification Metal-organic frameworks Metal-organic frameworks topology topology
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| GB/T 7714 | Zhang, Jian , Wang, Bin , Li, Ming et al. Different two-dimensional metal-organic frameworks through ligand modification [J]. | JOURNAL OF COORDINATION CHEMISTRY , 2016 , 69 (14) : 2193-2199 . |
| MLA | Zhang, Jian et al. "Different two-dimensional metal-organic frameworks through ligand modification" . | JOURNAL OF COORDINATION CHEMISTRY 69 . 14 (2016) : 2193-2199 . |
| APA | Zhang, Jian , Wang, Bin , Li, Ming , Zhao, Min-Jian , Xie, Ya-Bo , Li, Jian-Rong . Different two-dimensional metal-organic frameworks through ligand modification . | JOURNAL OF COORDINATION CHEMISTRY , 2016 , 69 (14) , 2193-2199 . |
| 导入链接 | NoteExpress RIS BibTex |
摘要 ：
金属有机多孔材料，包括具有无限拓展网络结构的金属有机骨架(MOFs)和有限分子笼结构的金属有机多面体/多边形(MOPs)，因其结构多样、容易可控合成等特征，近年来受到广泛关注，已成为化学和材料科学研究的前沿热点之一。其研究正呈现出方兴未艾的发展趋势。
关键词 ：
金属有机骨架(MOFs) 金属有机骨架(MOFs) 金属有机多面体(MOPs) 金属有机多面体(MOPs) 吸附分离 吸附分离 设计合成 设计合成
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| GB/T 7714 | 陈亚 , 吕修亮 , 杨帆 et al. 金属有机多面体与金属有机骨架的设计合成及潜在应用 [C] //第九届全国无机化学学术会议论文集 . 2015 : 1-1 . |
| MLA | 陈亚 et al. "金属有机多面体与金属有机骨架的设计合成及潜在应用" 第九届全国无机化学学术会议论文集 . (2015) : 1-1 . |
| APA | 陈亚 , 吕修亮 , 杨帆 , 赵翠 , 王彬 , 白彦 et al. 金属有机多面体与金属有机骨架的设计合成及潜在应用 第九届全国无机化学学术会议论文集 . (2015) : 1-1 . |
| 导入链接 | NoteExpress RIS BibTex |
关键词 ：
金属有机骨架(MOFs) 金属有机骨架(MOFs) 金属有机多面体(MOPs) 金属有机多面体(MOPs) 吸附分离 吸附分离 设计合成 设计合成
引用：
复制并粘贴一种已设定好的引用格式，或利用其中一个链接导入到文献管理软件中。
| GB/T 7714 | 陈亚 , 吕修亮 , 杨帆 et al. 金属有机多面体与金属有机骨架的设计合成及潜在应用 [C] //中国化学会第九届全国无机化学学术会议论文集-B配位化学 . 2015 . |
| MLA | 陈亚 et al. "金属有机多面体与金属有机骨架的设计合成及潜在应用" 中国化学会第九届全国无机化学学术会议论文集-B配位化学 . (2015) . |
| APA | 陈亚 , 吕修亮 , 杨帆 , 赵翠 , 王彬 , 白彦 et al. 金属有机多面体与金属有机骨架的设计合成及潜在应用 中国化学会第九届全国无机化学学术会议论文集-B配位化学 . (2015) . |
| 导入链接 | NoteExpress RIS BibTex |
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