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Disclosing the formation mechanisms of Ag-containing Laves phases at the atomic scale in an Al-Cu-Mg-Ag alloy SCIE
期刊论文 | 2024 , 184 , 111-121 | JOURNAL OF MATERIALS SCIENCE & TECHNOLOGY
摘要&关键词 引用

摘要 :

In addition to the three well-known Ag-related precipitates (, X' and Z) in the Al-Cu-Mg-Ag alloys, Ag can also be involved in the formation of the as-cast second phases. However, the effect of Ag addition in Al-Cu-Mg-Ag alloys has not been completely studied and even the structure of the as-cast Agcontaining phases is still controversial. By employing the focused ion beam (FIB) combined with transmission electron microscopy (TEM) techniques and density functional theory (DFT) calculations, the formation mechanisms of the Ag-containing phases in the as-cast Al-Cu-Mg-Ag alloys have been investigated. The Ag-containing phases are a series of hexagonal C14-type Laves phases with continuously varying Ag concentrations, described as (Alx Cuy Ag1-x-y)(2) Mg. Moreover, the specific occupancy sites of the atoms in (Alx Cuy Ag1-x-y)(2) Mg were determined. The formation of the (Alx Cuy Ag1-x-y )2 Mg can be attributed to the stronger Ag-induced aggregation of solute atoms in the initial stage and the establishment of strong Ag-X (X = Al, Mg and Ag) bonding in the Ag-containing phases. Furthermore, our experiments have revealed the solidification sequence of Al-Cu-Mg-Ag alloys, and pointed out that (Alx Cu-y Ag1-x-y)(2) Mg is formed at a lower temperature (493.9 degrees C) through the reaction L Al-2 CuMg + (Alx Cu-y Ag1-x-y)(2) Mg. The study could have positive implications for refinement of the Al-Cu-Mg-Ag quaternary phase diagram and promote the composition-property design of novel aluminum alloys based on (Alx Cuy Ag1-x-y)(2) Mg in the future. (c) 2023 Published by Elsevier Ltd on behalf of The editorial office of Journal of Materials Science & Technology.

关键词 :

Al-Cu-Mg-Ag alloys Al-Cu-Mg-Ag alloys Laves phases Laves phases Formation mechanisms Formation mechanisms HAADF-STEM HAADF-STEM First -principles calculation First -principles calculation

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GB/T 7714 Liu, Qilong , Li, Xiwu , Xiao, Wei et al. Disclosing the formation mechanisms of Ag-containing Laves phases at the atomic scale in an Al-Cu-Mg-Ag alloy [J]. | JOURNAL OF MATERIALS SCIENCE & TECHNOLOGY , 2024 , 184 : 111-121 .
MLA Liu, Qilong et al. "Disclosing the formation mechanisms of Ag-containing Laves phases at the atomic scale in an Al-Cu-Mg-Ag alloy" . | JOURNAL OF MATERIALS SCIENCE & TECHNOLOGY 184 (2024) : 111-121 .
APA Liu, Qilong , Li, Xiwu , Xiao, Wei , Li, Zhihui , Zhu, Kai , Wen, Kai et al. Disclosing the formation mechanisms of Ag-containing Laves phases at the atomic scale in an Al-Cu-Mg-Ag alloy . | JOURNAL OF MATERIALS SCIENCE & TECHNOLOGY , 2024 , 184 , 111-121 .
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一种直接热处理制备铂钴金属间化合物纳米颗粒的方法 incoPat
专利 | 2023-04-27 | CN202310466854.8
摘要&关键词 引用

摘要 :

本发明涉及一种直接热处理制备铂钴金属间化合物纳米颗粒的方法,属于电催化技术领域。本发明以2, 2'‑联二噻吩、六水合硝酸钴和二氧化硅为原料制备出催化剂载体,再将乙酰丙酮铂、乙酰丙酮钴和催化剂载体加入到去离子水中,超声混匀后蒸干溶剂得到前驱体粉末,将前驱体粉末置于H2/Ar混合气氛围中,在温度900~1100℃下恒温热处理1.5~2.5h,匀速降温至温度550~650℃并恒温热处理5~7h,得到Pt3Co金属间化合物纳米颗粒,即IMC‑Pt3Co/C。本发明通过热处理方法直接制备出尺度均一的Pt3Co金属间化合物纳米颗粒催化剂,Pt3Co有序相可以大大提高催化剂的催化活性。

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GB/T 7714 隋曼龄 , 沈志桐 , 卢岳 . 一种直接热处理制备铂钴金属间化合物纳米颗粒的方法 : CN202310466854.8[P]. | 2023-04-27 .
MLA 隋曼龄 et al. "一种直接热处理制备铂钴金属间化合物纳米颗粒的方法" : CN202310466854.8. | 2023-04-27 .
APA 隋曼龄 , 沈志桐 , 卢岳 . 一种直接热处理制备铂钴金属间化合物纳米颗粒的方法 : CN202310466854.8. | 2023-04-27 .
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一种钠离子电池层状正极材料的制备方法 incoPat
专利 | 2023-04-24 | CN202310443754.3
摘要&关键词 引用

摘要 :

本发明涉及一种钠离子电池层状正极材料的制备方法,属于钠离子电池技术领域。本发明将Na2CO3、NiO、Mn2O3、掺杂金属氧化物混合均匀得到混合粉A,混合粉A加入到易挥发溶剂中搅拌混合得到浆料A,浆料A烘干去除易挥发溶剂后压片,再置于温度500~1200℃烧结5~30h,随炉冷却至温度为不高于150℃得到正极材料粉末;将正极材料粉末、PVDF、乙炔黑混合均匀得到混合粉B,混合粉B中加入N‑甲基吡咯烷酮进行调浆得到浆料B,然后将浆料B涂覆在铝箔上,真空干燥得到极片;以极片为正极,金属钠或软碳为负极,NaClO4电解液为电池电解液,组装成钠离子电池并循环1~50圈,拆出电极得到循环后的极片,循环后的极片经热处理得到钠离子电池层状正极。该电极具有优异的循环稳定性。

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GB/T 7714 程苏兰 , 李金辉 , 隋曼龄 et al. 一种钠离子电池层状正极材料的制备方法 : CN202310443754.3[P]. | 2023-04-24 .
MLA 程苏兰 et al. "一种钠离子电池层状正极材料的制备方法" : CN202310443754.3. | 2023-04-24 .
APA 程苏兰 , 李金辉 , 隋曼龄 , 闫鹏飞 . 一种钠离子电池层状正极材料的制备方法 : CN202310443754.3. | 2023-04-24 .
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一种室温下催化甲醛高效降解的方法 incoPat
专利 | 2023-05-11 | CN202310529078.1
摘要&关键词 引用

摘要 :

本发明涉及一种室温下催化甲醛高效降解的方法,属于甲醛催化降解技术领域。本发明光催化剂为二氧化锰/铯锡碘量子点复合催化剂,二氧化锰与铯锡碘量子点溶液的固液比mg : μL为0.5~1 : 1;将纳米二氧化锰催化剂超声分散在正己烷溶剂中得到纳米二氧化锰催化剂分散液;将铯锡碘量子点加入到纳米二氧化锰催化剂分散液中,超声分散,使铯锡碘量子点均匀负载在纳米二氧化锰催化剂表面得到二氧化锰/铯锡碘量子点复合催化剂分散液;将二氧化锰/铯锡碘量子点复合催化剂分散液均匀涂布在载体上,然后涂布有二氧化锰/铯锡碘量子点复合催化剂的载体置于甲醛氛围中,在室温下,有光照或无光照条件下催化甲醛降解生成H2O和CO2。本发明复合催化剂可提高室温甲醛的降解效率。

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GB/T 7714 隋曼龄 , 包子涵 , 卢岳 . 一种室温下催化甲醛高效降解的方法 : CN202310529078.1[P]. | 2023-05-11 .
MLA 隋曼龄 et al. "一种室温下催化甲醛高效降解的方法" : CN202310529078.1. | 2023-05-11 .
APA 隋曼龄 , 包子涵 , 卢岳 . 一种室温下催化甲醛高效降解的方法 : CN202310529078.1. | 2023-05-11 .
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一种TiO2/Cs2AgBiBr6复合催化剂及其制备方法与应用 incoPat
专利 | 2023-05-11 | CN202310529010.3
摘要&关键词 引用

摘要 :

本发明涉及一种TiO2/Cs2AgBiBr6复合催化剂及其制备方法与应用,属于光催化技术领域。本发明TiO2/Cs2AgBiBr6复合催化剂由纳米TiO2催化剂和Cs2AgBiBr6晶体组成,纳米TiO2催化剂负载于Cs2AgBiBr6晶体表面。本发明将CsBr、AgBr和BiBr3研磨混合得到前驱体粉末;将前驱体粉末平铺在称量纸上,将称量纸漂浮在去离子水面使去离子水逐渐浸润前驱体粉末,浸润过程中前驱体粉末颜色由浅变深,颜色变化停止后,将浸润后的粉末取出,烘干即得Cs2AgBiBr6晶体粉末;将Cs2AgBiBr6晶体粉末和纳米TiO2催化剂加入到研磨容器中,在相对湿度>50%条件下湿磨5~10min纳米TiO2催化剂负载于Cs2AgBiBr6晶体表面得到TiO2/Cs2AgBiBr6复合催化剂。本发明TiO2纳米颗粒负载在Cs2AgBiBr6晶体上,有效促进光生电子的分离和转移,在可见光下高效催化CO2气体还原选择性转为CO气体。

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GB/T 7714 卢岳 , 梁贺贺 , 隋曼龄 . 一种TiO2/Cs2AgBiBr6复合催化剂及其制备方法与应用 : CN202310529010.3[P]. | 2023-05-11 .
MLA 卢岳 et al. "一种TiO2/Cs2AgBiBr6复合催化剂及其制备方法与应用" : CN202310529010.3. | 2023-05-11 .
APA 卢岳 , 梁贺贺 , 隋曼龄 . 一种TiO2/Cs2AgBiBr6复合催化剂及其制备方法与应用 : CN202310529010.3. | 2023-05-11 .
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Recent advances in in-situ transmission electron microscopy techniques for heterogeneous catalysis SCIE
期刊论文 | 2023 , 26 (7) | ISCIENCE
摘要&关键词 引用

摘要 :

The process of heterogeneous catalytic reaction under working conditions has long been considered a "black box", which is mainly because of the difficulties in directly characterizing the structural changes of catalysts at the atomic level during catalytic reactions. The development of in situ transmission electron mi-croscopy (TEM) techniques offers opportunities for introducing a realistic chem-ical reaction environment in TEM, making it possible to uncover the mystery of catalytic reactions. In this article, we present a comprehensive overview of the application of in situ TEM techniques in heterogeneous catalysis, highlighting its utility for observing gas-solid and liquid-solid reactions during thermal catal-ysis, electrocatalysis, and photocatalysis. in situ TEM has a unique advantage in revealing the complex structural changes of catalysts during chemical reactions. Revealing the real-time dynamic structure during reaction processes is crucial for understanding the intricate relationship between catalyst structure and its cata-lytic performance. Finally, we present a perspective on the future challenges and opportunities of in situ TEM in heterogeneous catalysis.

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GB/T 7714 Qu, Jiangshan , Sui, Manling , Li, Rengui . Recent advances in in-situ transmission electron microscopy techniques for heterogeneous catalysis [J]. | ISCIENCE , 2023 , 26 (7) .
MLA Qu, Jiangshan et al. "Recent advances in in-situ transmission electron microscopy techniques for heterogeneous catalysis" . | ISCIENCE 26 . 7 (2023) .
APA Qu, Jiangshan , Sui, Manling , Li, Rengui . Recent advances in in-situ transmission electron microscopy techniques for heterogeneous catalysis . | ISCIENCE , 2023 , 26 (7) .
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Direct approaches to distinguishing deformation and phase transformation structures in shock-loaded iron SCIE
期刊论文 | 2022 , 194 | MATERIALS CHARACTERIZATION
WoS核心集被引次数: 2
摘要&关键词 引用

摘要 :

An ??-Fe ??? ??-Fe phase transformation occurs in iron when the shock loading pressure exceeds 13 GPa, but all the ??-Fe will reverse back to ??-Fe during unloading, resulting in no residual ??-Fe in the unloaded samples. To prove the occurrence of this process, a series of microstructural characterization techniques were used to study the microstructures of shock-loaded iron, but hard to reach a consensus on the experimental results. Here, by using two conventional electron microscopy techniques, electron backscattered diffraction (EBSD) in scanning electron microscopy and selected area electron diffraction (SAED) in transmission electron microscopy, we reveal six novel phase transformation variants directly related to the reversible phase transformation. On this basis, the essential differences of microstructure between deformation area and phase transformation area are revealed. Further, we propose two fast and efficient methods which can identify the occurrence of the reversible phase transformation by EBSD and SAED, respectively. The universality of these methods has been verified in different shock loading experiments in iron.

关键词 :

EBSD EBSD ?-Fe??-Fe reversible phase transformation ?-Fe??-Fe reversible phase transformation Phase transformation variants Phase transformation variants Deformation twins Deformation twins Shock-loaded iron Shock-loaded iron

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GB/T 7714 Yu, Mingchao , Guo, Zhenxi , Meng, Xin et al. Direct approaches to distinguishing deformation and phase transformation structures in shock-loaded iron [J]. | MATERIALS CHARACTERIZATION , 2022 , 194 .
MLA Yu, Mingchao et al. "Direct approaches to distinguishing deformation and phase transformation structures in shock-loaded iron" . | MATERIALS CHARACTERIZATION 194 (2022) .
APA Yu, Mingchao , Guo, Zhenxi , Meng, Xin , Chen, Yongtao , Yu, Jidong , Sui, Manling . Direct approaches to distinguishing deformation and phase transformation structures in shock-loaded iron . | MATERIALS CHARACTERIZATION , 2022 , 194 .
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Direct Synthesis of Stable 1T-MoS2 Doped with Ni Single Atoms for Water Splitting in Alkaline Media SCIE
期刊论文 | 2022 , 18 (16) | SMALL
WoS核心集被引次数: 123
摘要&关键词 引用

摘要 :

Metallic MoS2 (i.e., 1T-MoS2) is considered as the most promising precious-metal-free electrocatalyst with outstanding hydrogen evolution reaction (HER) performance in acidic media comparable to Pt. However, sluggish kinematics of HER in alkaline media and its inability for the oxygen evolution reaction (OER), hamper its development as bifunctional catalysts. The instability of 1T-MoS2 further impedes its applications for scaling up, calling an urgent need for simple synthesis to produce stable 1T-MoS2. In this work, the challenge of 1T-MoS2 synthesis is first addressed using a direct one-step hydrothermal method by adopting ascorbic acid. 1T-MoS2 with flower-like morphology is obtained, and transition metals (Ni, Co, Fe) are simultaneously doped into 1T-MoS2. Ni-1T-MoS2 achieves an enhanced bifunctional catalytic activity for both HER and OER in alkaline media, where the key role of Ni doping as single atom is proved to be essential for boosting HER/OER activity. Finally, a Ni-1T-MoS2||Ni-1T-MoS2 electrolyzer is fabricated, reaching a current density of 10 mA cm(-2) at an applied cell voltage of only 1.54 V for overall water splitting.

关键词 :

(2) (2) overall water splitting overall water splitting bifunctional electrocatalysts bifunctional electrocatalysts hydrothermal synthesis hydrothermal synthesis 1T-MoS 1T-MoS doping doping

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GB/T 7714 Wang, Guowei , Zhang, Guikai , Ke, Xiaoxing et al. Direct Synthesis of Stable 1T-MoS2 Doped with Ni Single Atoms for Water Splitting in Alkaline Media [J]. | SMALL , 2022 , 18 (16) .
MLA Wang, Guowei et al. "Direct Synthesis of Stable 1T-MoS2 Doped with Ni Single Atoms for Water Splitting in Alkaline Media" . | SMALL 18 . 16 (2022) .
APA Wang, Guowei , Zhang, Guikai , Ke, Xiaoxing , Chen, Xiangyu , Chen, Xu , Wang, Yueshuai et al. Direct Synthesis of Stable 1T-MoS2 Doped with Ni Single Atoms for Water Splitting in Alkaline Media . | SMALL , 2022 , 18 (16) .
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Single metal atom oxide anchored Fe3O4-ED-rGO for highly efficient photodecomposition of antibiotic residues under visible light illumination SCIE
期刊论文 | 2022 , 300 | APPLIED CATALYSIS B-ENVIRONMENTAL
WoS核心集被引次数: 34
摘要&关键词 引用

摘要 :

Designing highly efficient photocatalysts is significantly important to degrade the harmful pollutions in water. In this study, photocatalyst of Fe3O4-ED-rGO with dissolved HPV was successfully prepared and electron microscopy characterization revealed that large number of single tungsten/vanadium atom oxide (ST/VAO) was homogeneously deposited on Fe3O4 nanoparticles in SMAO-MrGO-ED sample and occupied the bivalent Fe2+ sites. Meanwhile, phase analysis confirmed that the Fe3O4 nanocomposites were mostly conversed from the reducted Fe2O3 by the hydrolysis of rGO-ED-HPV. Such a highly dispersed monatomic adsorption on the bivalent Fe2+ of polycrystalline SMAO-MrGO-ED nanocomposite not only benefits for the visible light absorption from 2.7 eV to 2.10 eV, but also offers abundantly active sites to get the highest activity of 98.43% and 98.12% for ciprofloxacin (CF) and ibuprofen (IBF) photodegradation, respectively. All these discoveries give us a new insight to design the photocatalysts with high photodegradation efficiency, low cost, short reaction time and good reusability.

关键词 :

Ibuprofen Ibuprofen Magnetic nanocomposite Magnetic nanocomposite Single metal atom oxide Single metal atom oxide Photodegradation Photodegradation Ciprofloxacin Ciprofloxacin

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GB/T 7714 Selvakumar, Karuppaiah , Wang, Yueshuai , Lu, Yue et al. Single metal atom oxide anchored Fe3O4-ED-rGO for highly efficient photodecomposition of antibiotic residues under visible light illumination [J]. | APPLIED CATALYSIS B-ENVIRONMENTAL , 2022 , 300 .
MLA Selvakumar, Karuppaiah et al. "Single metal atom oxide anchored Fe3O4-ED-rGO for highly efficient photodecomposition of antibiotic residues under visible light illumination" . | APPLIED CATALYSIS B-ENVIRONMENTAL 300 (2022) .
APA Selvakumar, Karuppaiah , Wang, Yueshuai , Lu, Yue , Tian, Bohai , Zhang, Zeyu , Hu, Jingcong et al. Single metal atom oxide anchored Fe3O4-ED-rGO for highly efficient photodecomposition of antibiotic residues under visible light illumination . | APPLIED CATALYSIS B-ENVIRONMENTAL , 2022 , 300 .
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一种废旧锂电池正极材料剥离并直接再生的方法 incoPat
专利 | 2022-12-13 | CN202211601633.9
摘要&关键词 引用

摘要 :

本发明涉及一种废旧锂电池正极材料剥离并直接再生的方法,属于锂电池正极技术领域。本发明机械拆解废旧锂电池正极得到含Al集流体的正极极片,在含Al集流体的正极极片表面喷涂锂盐溶液形成锂盐薄膜,烘干得到补锂正极极片;在空气氛围下,补锂正极极片进行低温焙烧,敲打物理分离得到废旧LiCoO2正极材料,废旧LiCoO2正极材料研磨过筛得到粉末A;将粉末A加入到NaOH溶液中碱浸除铝得到粉末B;将过量锂盐加入到粉末B中混合均匀,在空气氛围中高温烧结得到再生锂电池正极材料。相比较传统正极材料剥离的方式,低温补锂法高效的将正极材料与铝箔分离,所再生的LiCoO2正极材料满足工业化应用。

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GB/T 7714 闫鹏飞 , 隋曼龄 , 牟许霖 et al. 一种废旧锂电池正极材料剥离并直接再生的方法 : CN202211601633.9[P]. | 2022-12-13 .
MLA 闫鹏飞 et al. "一种废旧锂电池正极材料剥离并直接再生的方法" : CN202211601633.9. | 2022-12-13 .
APA 闫鹏飞 , 隋曼龄 , 牟许霖 , 董恩华 , 黄开 . 一种废旧锂电池正极材料剥离并直接再生的方法 : CN202211601633.9. | 2022-12-13 .
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