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学者姓名：孙继红
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Abstract ：
The MOF-5@clinoptilolite (MOF@CP) composites are successfully synthesized using polyvinylpyrrolidone (PVP) for adsorption separation of CO2/CH4, CO2/N-2, and CH4/N-2. The effects of the PVP amounts on the dispersity of MOF-5 on CP random lamellas of the MOF@CPs are evaluated via various characterizations. Meanwhile, their single-component gas adsorption isotherms, breakthrough experiments, and cycling test are measured. The results elucidate that the used PVP amount has a significant influence on the particle size and the uniformity of MOF-5 dispersed on CP random lamellas. The MOF-5-loaded amount in MOF@CP is estimated to be up to 42.52 wt.%. Especially, the surface fractal evolutions indicated the surfaces of MOF@CP became from rough to smooth with the increase of PVP. The CO2/CH4, CO2/N-2, and CH4/N-2 selectivity factors of MOF@CP are higher than that of CP, displaying a better separation performance. Their cycling test revealed that MOF@CPs could be used repetitively, highlighting efficiency for CO2 and CH4 separation. Meanwhile, the MOF-5@CP stability under moisture is preliminarily investigated, showing higher moisture resistance stability than MOF-5. Additionally, the grand canonical Monte Carlo simulations demonstrated the adsorption separation mechanism of the prepared MOF@CPs.
Keyword ：
adsorption separation adsorption separation MOF-5 MOF-5 polyvinylpyrrolidone polyvinylpyrrolidone fractal fractal clinoptilolites clinoptilolites
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| GB/T 7714 | Zhou, Jiawei , Liu, Ming , Bai, Shiyang et al. Well-Dispersed MOF-5 on The Polyvinylpyrrolidone-Coated Random Lamellas of Clinoptilolites for Adsorptive Separation Performance of CO2, CH4, and N2 [J]. | ADVANCED SUSTAINABLE SYSTEMS , 2024 , 8 (7) . |
| MLA | Zhou, Jiawei et al. "Well-Dispersed MOF-5 on The Polyvinylpyrrolidone-Coated Random Lamellas of Clinoptilolites for Adsorptive Separation Performance of CO2, CH4, and N2" . | ADVANCED SUSTAINABLE SYSTEMS 8 . 7 (2024) . |
| APA | Zhou, Jiawei , Liu, Ming , Bai, Shiyang , Sun, Jihong , Wei, Jia , Wang, Ju . Well-Dispersed MOF-5 on The Polyvinylpyrrolidone-Coated Random Lamellas of Clinoptilolites for Adsorptive Separation Performance of CO2, CH4, and N2 . | ADVANCED SUSTAINABLE SYSTEMS , 2024 , 8 (7) . |
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Abstract ：
Using natural clinoptilolite (NCP) as a carrier and alginate (Alg)-calcium as an active species, the porous silicon calcium alginate nanocomposite (Alg-Ca-NCP) was successfully fabricated via adsorption-covalence-hydrogen bond. Its structural features and physicochemical properties were detailed investigated by various characterizations. The results indicated that Alg-Ca-NCP presented the disordered lamellar structures with approximately uniform particles in size of 300 - 500 nm. Specially, their surface fractal evolutions between the irregular roughness and dense structures were demonstrated via the SAXS patterns. The results elucidated that the abundant micropores of NCP were beneficial for unrestricted diffusing of Alg -Ca, which was conducive to facilitate a higher loading and sustainable releasing. The Ca content of leaf mustard treated with Alg-Ca-NCP-0.5 was 484.5 mg/100g on the 21st day, higher than that by water (CK) and CaCl 2 solution treatments, respectively. Meanwhile, the prepared Alg-Ca-NCPs presented the obvious anti-aging effects on peroxidase drought stress of mustard leaves. These demonstrations provided a simple and effective method to synthesize Alg-Ca-NCPs as delivery nanocomposites, which is useful to improve the weak absorption and low utilization of calcium alginate by plants.
Keyword ：
Leaf mustard Leaf mustard Controlled alginate delivery Controlled alginate delivery Natural clinoptilolite Natural clinoptilolite Cauliflower Cauliflower Fractal structure Fractal structure
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| GB/T 7714 | Yan, Guofu , Zhou, Jiawei , Cui, Xueqing et al. Physicochemical properties and fractal characterizations of the functionalized porous clinoptilolites for controlling alginate delivery in growing cauliflower and leaf mustard [J]. | PLANT PHYSIOLOGY AND BIOCHEMISTRY , 2024 , 211 . |
| MLA | Yan, Guofu et al. "Physicochemical properties and fractal characterizations of the functionalized porous clinoptilolites for controlling alginate delivery in growing cauliflower and leaf mustard" . | PLANT PHYSIOLOGY AND BIOCHEMISTRY 211 (2024) . |
| APA | Yan, Guofu , Zhou, Jiawei , Cui, Xueqing , Liu, Ming , Bai, Shiyang , Sun, Jihong et al. Physicochemical properties and fractal characterizations of the functionalized porous clinoptilolites for controlling alginate delivery in growing cauliflower and leaf mustard . | PLANT PHYSIOLOGY AND BIOCHEMISTRY , 2024 , 211 . |
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Abstract ：
本发明公开了一种用于催化二氧化碳与环氧化物进行环加成反应的共聚物的制备方法，该共聚物为丙烯酸与1‑乙烯基咪唑的共聚物；该制备方法，包括：在磁力搅拌下，将水相滴加到油相中，并将乳液进行加热、保温；其中，水相包括丙烯酸、1‑乙烯基咪唑和水，油相包括液体石蜡和乳化剂；向乳液中加入偶氮二异丁腈，保温进行反应；反应结束后，冷却至室温、离心分离、洗涤，然后冷冻干燥以除去残留的溶剂和水，得到共聚物。本发明所制得的共聚物含有咪唑基团和可在有机溶剂中稳定存在并溶胀的交联网络，可作为多相催化剂，无需添加助催化剂和有机溶剂，即可进行二氧化碳与环氧化物的环加成反应生成环状碳酸酯。
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| GB/T 7714 | 白诗扬 , 庄园野 , 孙继红 et al. 一种用于催化二氧化碳与环氧化物进行环加成反应的共聚物的制备方法 : CN202310774394.5[P]. | 2023-06-28 . |
| MLA | 白诗扬 et al. "一种用于催化二氧化碳与环氧化物进行环加成反应的共聚物的制备方法" : CN202310774394.5. | 2023-06-28 . |
| APA | 白诗扬 , 庄园野 , 孙继红 , 葛梦 . 一种用于催化二氧化碳与环氧化物进行环加成反应的共聚物的制备方法 : CN202310774394.5. | 2023-06-28 . |
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Abstract ：
本发明公开了一种在斜发沸石表面原位生长微晶的复合材料制备方法，包括：先利用表面活性剂及其水热合成方法改性斜发沸石，并分别采用无机酸溶液处理和硅烷偶联剂修饰将有机配体嫁接在改性斜发沸石的表面，从而通过配位键将微晶与斜发沸石进行复合，以制得斜发沸石与微晶复合材料。该复合材料可有效的改善单一斜发沸石比表面积较小的问题，从而增强了气体的吸附分离能力，该方法通过共价键在斜发沸石表面原位复合微晶，增强了微晶与斜发沸石之间的相互作用力，从而使得复合材料结构更加稳定，在纯化煤层气(吸附分离甲烷与氮气)中表现出较强的应用潜力。
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| GB/T 7714 | 孙继红 , 周嘉伟 , 崔雪晴 et al. 一种在斜发沸石表面原位生长微晶的复合材料制备方法 : CN202310529672.0[P]. | 2023-05-11 . |
| MLA | 孙继红 et al. "一种在斜发沸石表面原位生长微晶的复合材料制备方法" : CN202310529672.0. | 2023-05-11 . |
| APA | 孙继红 , 周嘉伟 , 崔雪晴 , 刘明 , 白诗扬 . 一种在斜发沸石表面原位生长微晶的复合材料制备方法 : CN202310529672.0. | 2023-05-11 . |
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Abstract ：
本发明公开了一种斜发沸石与微晶复合材料的制备方法，包括：将碱源、硅源、铝源、水、表面活性剂混合均匀并搅拌至澄清，得到溶液Ⅰ；将晶种加入到溶液Ⅰ中进行水热晶化，反应完成后冷却至室温，并经固液分离、洗涤、干燥，得到固体Ⅰ；将固体Ⅰ、高分子分散剂、可溶金属盐、有机配体和有机溶剂通过超声振荡且混合均匀后，得到溶液Ⅱ；将溶液Ⅱ进行溶剂热反应，反应完成后冷却至室温，并经固液分离、洗涤、干燥，得到斜发沸石与微晶复合材料。本发明具有反应时间短、产率高、能耗低、操作简单，易于工业化生产的特点，在纯化煤层气(吸附分离甲烷与氮气)中表现出较强的应用潜力。
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| GB/T 7714 | 孙继红 , 周嘉伟 , 崔雪晴 et al. 一种斜发沸石与微晶复合材料的制备方法 : CN202310529665.0[P]. | 2023-05-11 . |
| MLA | 孙继红 et al. "一种斜发沸石与微晶复合材料的制备方法" : CN202310529665.0. | 2023-05-11 . |
| APA | 孙继红 , 周嘉伟 , 崔雪晴 , 刘明 , 白诗扬 . 一种斜发沸石与微晶复合材料的制备方法 : CN202310529665.0. | 2023-05-11 . |
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Abstract ：
The pH-responsive fluorescent P(1,8-naphthalic anhydride (NA)-acrylic acid (AA)) matrix was successfully prepared by a doping method using poly(acrylic acid) (PAA) as a pH-sensitive polymer and NA as a fluorescent tracer. The fluorescent behaviors of the used NA dispersed in PAA frameworks were demonstrated based on fractal features combined with various characterizations, such as small-angle X-ray scattering (SAXS) patterns, photoluminescence (PL) spectra, scanning electron microscope (SEM) images, thermogravimetry (TG) profiles, Fourier transform infrared (FT-IR) spectroscopy, and time-resolved decays. The effects of NA-doping on the representative fluorescent P(NA-AA) were investigated, in which the fluorescent performance of the doped NA was emphasized. The results indicated that aggregated clusters of the doped NA were gradually serious with an increase in NA doping amount or extension of NA doping time, accompanied by an increase in mass fractal dimension (D-m) values. Meanwhile, the doped NA presented stable fluorescent properties during the swelling-shrinking process of PAA. Ibuprofen (IBU) was used as a model drug, and fractal evolutions of the obtained P(NA-AA) along with the drug loading and releasing behaviors were evaluated via SAXS patterns, in which the drug-loaded P(NA-AA) presented surface fractal (D-s) characteristics, while the D-m value varied from 2.94 to 2.58 during sustained drug-release in pH 2.0, indicating occurrences of its structural transformation from dense to loose with extension of IBU-releasing time. Finally, the cytotoxicity and cellular uptake behaviors of the obtained P(NA-AA) were preliminarily explored. These demonstrations revealed that the resultant P(NA-AA) should be a potential intelligent-responsive drug carrier for targeted delivery.
Keyword ：
drug delivery drug delivery fractal fractal fluorescence fluorescence pH-sensitive pH-sensitive dispersion dispersion poly(acrylic acid) poly(acrylic acid) 1 1 8-naphthalic anhydride 8-naphthalic anhydride
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| GB/T 7714 | Cui, Xueqing , Wang, Xiaoli , Xu, Xiaohuan et al. Dispersion Performances and Fluorescent Behaviors of Naphthalic Anhydride Doped in Poly(acrylic acid) Frameworks for pH-Sensitive Ibuprofen Delivery via Fractal Evolution [J]. | POLYMERS , 2023 , 15 (3) . |
| MLA | Cui, Xueqing et al. "Dispersion Performances and Fluorescent Behaviors of Naphthalic Anhydride Doped in Poly(acrylic acid) Frameworks for pH-Sensitive Ibuprofen Delivery via Fractal Evolution" . | POLYMERS 15 . 3 (2023) . |
| APA | Cui, Xueqing , Wang, Xiaoli , Xu, Xiaohuan , Xu, Bang , Sun, Jihong , Bai, Shiyang . Dispersion Performances and Fluorescent Behaviors of Naphthalic Anhydride Doped in Poly(acrylic acid) Frameworks for pH-Sensitive Ibuprofen Delivery via Fractal Evolution . | POLYMERS , 2023 , 15 (3) . |
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Abstract ：
Using poly(acrylic acid) (abbreviated as PAA) as a shell, bimodal mesoporous silicas (ab-breviated as BMMs) as a core, and bipyridine-proline (abbreviated as Z) as an active species, a facile approach for preparation of the P-Z@BMMs nanocomposites with core-shell structure was proposed, which was used as a suitable pH-sensitive catalyst for asymmetric aldol reaction between p-nitrobenzaldehyde and cyclohexanone. Their microstructural features and physicochem-ical properties were extensively characterized by various methods, such as powder X-ray diffraction patterns, N2 adsorption-desorption isotherms, the scanning (and transmission) electron microscopy images, the dynamic light scattering measurements, the thermogravimetric analysis, the elemental analysis, and the Fourier transform infrared spectroscopy spectra. Particularly, their fractal evolu-tion, the pair distance distribution function, and the Porod plots were demonstrated via the small -angle X-ray scattering patterns. The results elucidated that the PAA was successfully incorporated onto the external amino-modified surfaces of the mesoporous BMMs, and the particles having PAA grafted thereon had a pH-responsive shell in thickness of around 0.97 nm for controlled release of Z species by adjusting pH value of the reaction medium. Besides, the synthesized P-Z@BMMs pre-sented the satisfactory catalytic yields (around 80%) in comparison with the homo-and heteroge-neous catalytic system using Z or Z@BMMs as the catalysts.(c) 2023 The Author(s). Published by Elsevier B.V. on behalf of King Saud University. This is an open access article under the CC BY license (http://creativecommons.org/licenses/by/4.0/).
Keyword ：
pH -sensitive pH -sensitive Bimodal mesoporous silicas Bimodal mesoporous silicas Asymmetric aldol reaction Asymmetric aldol reaction Bipyridine-proline Bipyridine-proline Fractal characteristic Fractal characteristic
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| GB/T 7714 | Xu, Guangpeng , Jia, Bingying , Xu, Bang et al. Fractal features of pH-sensitive bimodal mesoporous silica-supported bipyridine-proline organocatalysts with core-shell structure and their application in asymmetric aldol reaction [J]. | ARABIAN JOURNAL OF CHEMISTRY , 2023 , 16 (8) . |
| MLA | Xu, Guangpeng et al. "Fractal features of pH-sensitive bimodal mesoporous silica-supported bipyridine-proline organocatalysts with core-shell structure and their application in asymmetric aldol reaction" . | ARABIAN JOURNAL OF CHEMISTRY 16 . 8 (2023) . |
| APA | Xu, Guangpeng , Jia, Bingying , Xu, Bang , Bai, Shiyang , Sun, Jihong , Munir, Tallat . Fractal features of pH-sensitive bimodal mesoporous silica-supported bipyridine-proline organocatalysts with core-shell structure and their application in asymmetric aldol reaction . | ARABIAN JOURNAL OF CHEMISTRY , 2023 , 16 (8) . |
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Abstract ：
The bimetallic ion exchanged clinoptilolites (M1xM2y-CPs, M1 = Li+, Na+ or Cs+, M2 = Li+ or Cs+, x, and y = the exchange degree of the first and second cation) were prepared. Their physic-chemical parameters were characterized using various methods. The results demonstrated that the relative crystallinity of M1xM2y-CPs gradually decreased with the increase of the secondary cationic introduction. Meanwhile, M1xM2y-CPs presented the surface fractal features, particularly, the values of M1xM2y-CPs were higher than that of single ion exchanged CPs, suggesting that the surface of M1xM2y-CPs was rougher and more disordered. The effects of the type, size, and distributions of the used various cations on the gas adsorption and separation properties were evaluated via their equilibrium adsorbed performances of CO2 and CH4 demonstrate. The results indicated that the CO2 uptake of NaxLiy-CP increased with the increase of Li+ exchange degree, in which, Na67.95Li17.15-CP presented the maximum adsorption capacity of 2.45 mmol/g for CO2. While, the CO2/CH4 selective factors of NaxCsy-CP were around 10.82-12.75 at 273 K and 9.92-12.44 at 298 K, much higher than that of other bimetallic ion exchanged samples. The breakthrough experiments displayed a longer breakthrough time and a stronger CO2 absorption capacity. The cycling tests indicated an excellent CO2 adsorption stability and reversibility. Furthermore, the kinetics adsorption of pseudo-first-order and intraparticle model were used to investigate their adsorption mechanism. Finally, the CO2 adsorption mechanism between the adsorption amount and the average total energy of the CO2 adsorption system was preliminary elucidated using Material Studio simulation software.
Keyword ：
Clinoptilolites Clinoptilolites CO 2 adsorption CO 2 adsorption Gas separation Gas separation CO 2 /CH 4 mixture CO 2 /CH 4 mixture Bimetallic ion exchange Bimetallic ion exchange
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| GB/T 7714 | Chen, Xue , Zhou, Jiawei , Wei, Jia et al. Performance evaluation of bimetallic ion exchanged clinoptilolite for potential equilibrium and kinetic adsorption separations of CO2 from CO2/ CH4 mixture [J]. | SEPARATION AND PURIFICATION TECHNOLOGY , 2023 , 331 . |
| MLA | Chen, Xue et al. "Performance evaluation of bimetallic ion exchanged clinoptilolite for potential equilibrium and kinetic adsorption separations of CO2 from CO2/ CH4 mixture" . | SEPARATION AND PURIFICATION TECHNOLOGY 331 (2023) . |
| APA | Chen, Xue , Zhou, Jiawei , Wei, Jia , Cui, Xueqing , Wan, Chunlei , Liu, Ming et al. Performance evaluation of bimetallic ion exchanged clinoptilolite for potential equilibrium and kinetic adsorption separations of CO2 from CO2/ CH4 mixture . | SEPARATION AND PURIFICATION TECHNOLOGY , 2023 , 331 . |
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Abstract ：
Fe(III)-modified clinoptilolites (Fe-CPs) were prepared by hydrothermal treatment. The collapse of the heulandite skeletons was avoided by adjusting the pH value using HCl solution, showing the maximum relative crystallinity of the Fe-CPs at an optimal pH of 1.3. The competitive exchange performances between Fe3+ ions and H+ with Na+ (and K+) suggested that the exchange sites were more easily occupied by H+. Various characterizations verified that the hydrothermal treatments had a strong influence on the dispersion and morphology of the isolated and clustered Fe species. The high catalytic activity of the oxygen evolution reaction indicated the insertion of Fe3+ into the skeletons and the occurrences of isomorphic substitution. The fractal evolutions revealed that hydrothermal treatments with the increase of Fe content strongly affected the morphologies of Fe species with rough and disordered surfaces. Meanwhile, the Fe(III)-modified performances of the CPs were systematically investigated, showing that the maximum Fe-exchange capacity was up to 10.6 mg/g. Their thermodynamic parameters and kinetic performances suggested that the Fe(III)-modified procedures belonged to spontaneous, endothermic, and entropy-increasing behaviors. Finally, their adsorption capacities of CO2 at 273 and 298 K were preliminarily evaluated, showing high CO2 adsorption capacity (up to 1.67 mmol/g at 273 K).
Keyword ：
clinoptilolite clinoptilolite adsorptive separations adsorptive separations isomorphous substitution isomorphous substitution Fe species Fe species extra-framework Fe extra-framework Fe fractal structures fractal structures
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| GB/T 7714 | Wan, Chunlei , Cui, Xueqing , Liu, Ming et al. Structure Features and Physicochemical Performances of Fe-Contained Clinoptilolites Obtained via the Aqueous Exchange of the Balanced Cations and Isomorphs Substitution of the Heulandite Skeletons for Electrocatalytic Activity of Oxygen Evolution Reaction and Adsorptive Performance of CO2 [J]. | MOLECULES , 2023 , 28 (7) . |
| MLA | Wan, Chunlei et al. "Structure Features and Physicochemical Performances of Fe-Contained Clinoptilolites Obtained via the Aqueous Exchange of the Balanced Cations and Isomorphs Substitution of the Heulandite Skeletons for Electrocatalytic Activity of Oxygen Evolution Reaction and Adsorptive Performance of CO2" . | MOLECULES 28 . 7 (2023) . |
| APA | Wan, Chunlei , Cui, Xueqing , Liu, Ming , Xu, Bang , Sun, Jihong , Bai, Shiyang . Structure Features and Physicochemical Performances of Fe-Contained Clinoptilolites Obtained via the Aqueous Exchange of the Balanced Cations and Isomorphs Substitution of the Heulandite Skeletons for Electrocatalytic Activity of Oxygen Evolution Reaction and Adsorptive Performance of CO2 . | MOLECULES , 2023 , 28 (7) . |
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Abstract ：
本发明公开了一种基于天然斜发沸石同步脱氮除磷吸附剂材料的制备方法及应用，包括：将天然斜发沸石粉碎至粒径为5‑10mm的颗粒，常温下用水浸泡，并置于超声波震荡0.5‑1h；在超声波震荡体系中，加入含有有机改性剂的水溶液后继续超声波震荡0.5‑1h；过滤得到吸附剂材料。本发明所制备的吸附剂材料针对高浓度氮磷废水，能够同步高效脱氮除磷，对氨氮脱除率在97％以上、总磷脱除率在85％以上，减少水体的富营养化发生；而且具有生产工艺简单，操作方便，设备较少，成本低等实际应用价值。
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| GB/T 7714 | 孙继红 , 陈雪 , 李业宏 et al. 基于天然斜发沸石同步脱氮除磷吸附剂材料的制备方法及应用 : CN202210348963.5[P]. | 2022-04-01 . |
| MLA | 孙继红 et al. "基于天然斜发沸石同步脱氮除磷吸附剂材料的制备方法及应用" : CN202210348963.5. | 2022-04-01 . |
| APA | 孙继红 , 陈雪 , 李业宏 , 郑乐辰 , 李泽凯 , 李嘉豪 . 基于天然斜发沸石同步脱氮除磷吸附剂材料的制备方法及应用 : CN202210348963.5. | 2022-04-01 . |
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