• Complex
  • Title
  • Keyword
  • Abstract
  • Scholars
  • Journal
  • ISSN
  • Conference
搜索
High Impact Results & Cited Count Trend for Year Keyword Cloud and Partner Relationship

Query:

学者姓名:陈标华

Refining:

Type

Submit Unfold

Co-Author

Submit Unfold

Clean All

Sort by:
Default
  • Default
  • Title
  • Year
  • WOS Cited Count
  • Impact factor
  • Ascending
  • Descending
< Page ,Total 8 >
Highly efficient lithium extraction from magnesium-rich brines with ionic liquid-based collaborative extractants: Thermodynamics and molecular insights SCIE
期刊论文 | 2024 , 286 | CHEMICAL ENGINEERING SCIENCE
Abstract&Keyword Cite

Abstract :

Selective extraction of Li+ from high Mg2+/Li+ ratio brines with ionic liquid (IL) based collaborative extractants was investigated by experiments, thermodynamic analyses, and quantum chemical (QC) calculations. Effects of different IL cationic structures and organophosphorus ligands on extraction performances were studied. The results demonstrated that the system 1-(2-hydroxyethyl)-3-methylimidazolium bis(trifluoromethylsulfonyl) imide + trioctyl phosphate ([HOEMIM][Tf2N] + TOP) was considered as the best extractant, with the very high extraction efficiency of Li+ (83.16 %) and separation selectivity of Li+/Mg2+ (742.11), which is higher than values reported in literature. The thermodynamic model ePC-SAFT was first extended to quantitatively predict the phase equilibria of the so-called "organic-inorganic complex strong electrolyte system" presented in this work. The molecular-level extraction mechanism was explored by QC calculation, indicating that the strong multi-site intermolecular interactions between Li+ and [HOEMIM][Tf2N] + TOP break the Li+ hydration. This work provides guidance to rationally design novel IL-based extractants for efficient extraction of Li+

Keyword :

Quantum chemical calculation Quantum chemical calculation Molecular mechanism Molecular mechanism Ionic liquid Ionic liquid Extraction of lithium Extraction of lithium ePC-SAFT ePC-SAFT

Cite:

Copy from the list or Export to your reference management。

GB/T 7714 Yu, Gangqiang , Zhang, Xinhe , Hubach, Tobias et al. Highly efficient lithium extraction from magnesium-rich brines with ionic liquid-based collaborative extractants: Thermodynamics and molecular insights [J]. | CHEMICAL ENGINEERING SCIENCE , 2024 , 286 .
MLA Yu, Gangqiang et al. "Highly efficient lithium extraction from magnesium-rich brines with ionic liquid-based collaborative extractants: Thermodynamics and molecular insights" . | CHEMICAL ENGINEERING SCIENCE 286 (2024) .
APA Yu, Gangqiang , Zhang, Xinhe , Hubach, Tobias , Chen, Biaohua , Held, Christoph . Highly efficient lithium extraction from magnesium-rich brines with ionic liquid-based collaborative extractants: Thermodynamics and molecular insights . | CHEMICAL ENGINEERING SCIENCE , 2024 , 286 .
Export to NoteExpress RIS BibTex
CO2 Oxidative Dehydrogenation of Propane to Olefin over Cr-M (M = Zr, La, Fe) Based Zeolite Catalyst SCIE
期刊论文 | 2024 , 14 (6) | CATALYSTS
Abstract&Keyword Cite

Abstract :

CO2 oxidative dehydrogenation of propane (CO2-ODHP), being not only favorable for olefin production but also beneficial for CO2 emission control, has recently attracted great attention. Here, a series of single metal (Cr) and bimetal (Zr, La, Fe) modified ZSM-5 zeolites were prepared via an impregnation method. It was found that the bimetal modified ZSM-5 possessed much higher C3H8 and CO2 conversion than that of monometallic modified Cr-3%-ZSM-5 (Cr3%-Z5), especially for Cr3%Zr2%-ZSM-5 (Cr3%Zr2%-Z5), which displayed the highest activity (w65.4%) and olefin yield (1.65 x 10(3) mu mol.g(cat)(-1) h(-1)). Various characterizations were performed, including XRD, N-2 adsorption-desorption, H2-TPR, Raman, XPS, HAAD-STEM, and TEM. It was revealed that Zr not only favored an improvement in the redox ability of Cr, but also contributed to the surface dispersion of loaded Cr species, constituting two major reasons explaining the superior activity of Cr3%Zr2%-Z5. To further improve CO2-ODHP catalytic behavior, a series of Cr3%-ZSM-5@SBA-15-n composite zeolite catalysts with diverse (ZSM-5/SBA-15) mass ratios were prepared (Cr-3%-ZS-n, n = 0.5, 2, 6, 16), which screened out an optimum mass ratio of six. Based on this, the Cr-3% Zr2%-ZS-6 compound was further prepared, and it eventually achieved even higher CO2-ODHP activity (76.9%) and olefin yield (1.72 x 10(3) mu mol.g(-1) cat h(-1)). Finally, the CO2-ODHP reaction mechanism was further investigated using in situ FTIR, and it was found that the reaction followed the Mars-van Krevelen mechanism, wherein CO2 participated in the reaction through generation of polydentate carbonates. The Cr6+ constituted as the active site, which was reduced to Cr3+ after the dihydrogen reaction, and was then further oxidized into Cr6+ by CO2, forming polydentate carbonates, and thus cycling the reactive species C-r6+. Additionally, assisted by a Bronsted acid site (favoring breaking of the C-C bond), C2H4 and CH4 were produced.

Keyword :

propane oxidative to olefin propane oxidative to olefin molecular sieve catalysts molecular sieve catalysts chromium-based catalysts chromium-based catalysts CO2 CO2

Cite:

Copy from the list or Export to your reference management。

GB/T 7714 Xing, Mingqiao , Liu, Ning , Dai, Chengna et al. CO2 Oxidative Dehydrogenation of Propane to Olefin over Cr-M (M = Zr, La, Fe) Based Zeolite Catalyst [J]. | CATALYSTS , 2024 , 14 (6) .
MLA Xing, Mingqiao et al. "CO2 Oxidative Dehydrogenation of Propane to Olefin over Cr-M (M = Zr, La, Fe) Based Zeolite Catalyst" . | CATALYSTS 14 . 6 (2024) .
APA Xing, Mingqiao , Liu, Ning , Dai, Chengna , Chen, Biaohua . CO2 Oxidative Dehydrogenation of Propane to Olefin over Cr-M (M = Zr, La, Fe) Based Zeolite Catalyst . | CATALYSTS , 2024 , 14 (6) .
Export to NoteExpress RIS BibTex
Recent Modification Strategies of MoS2 towards Electrocatalytic Hydrogen Evolution SCIE
期刊论文 | 2024 , 14 (2) | CATALYSTS
Abstract&Keyword Cite

Abstract :

Hydrogen production by the electrolysis of water is a green and efficient method, which is of great significance for achieving sustainable development. Molybdenum disulfide (MoS2) is a promising electrocatalyst for hydrogen evolution reaction (HER) due to its high electrochemical activity, low cost, and abundant reserves. In comparison to the noble metal Pt, MoS2 has poorer hydrogen evolution performance in water electrolysis. Therefore, further modifications of MoS2 need to be developed aiming at improving its catalytic performance. The present work summarizes the modification strategies that have been developed in the past three years on hydrogen evolution from water electrolysis by utilizing MoS2 as the electrocatalyst and following the two aspects of internal and external modifications. The former includes the strategies of interlayer spacing, sulfur vacancy, phase transition, and element doping, while the latter includes the heterostructure and conductive substrate. If the current gap in this paper's focus on modification strategies for electrocatalytic hydrogen evolution in water electrolysis is addressed, MoS2 will perform best in acidic or alkaline media. In addition to that, the present work also discusses the challenges and future development directions of MoS2 catalysts.

Keyword :

modification strategies modification strategies molybdenum disulfide molybdenum disulfide hydrogen evolution reaction hydrogen evolution reaction

Cite:

Copy from the list or Export to your reference management。

GB/T 7714 Liu, Lei , Liu, Ning , Chen, Biaohua et al. Recent Modification Strategies of MoS2 towards Electrocatalytic Hydrogen Evolution [J]. | CATALYSTS , 2024 , 14 (2) .
MLA Liu, Lei et al. "Recent Modification Strategies of MoS2 towards Electrocatalytic Hydrogen Evolution" . | CATALYSTS 14 . 2 (2024) .
APA Liu, Lei , Liu, Ning , Chen, Biaohua , Dai, Chengna , Wang, Ning . Recent Modification Strategies of MoS2 towards Electrocatalytic Hydrogen Evolution . | CATALYSTS , 2024 , 14 (2) .
Export to NoteExpress RIS BibTex
The copper size effect of CuZn/CeO2 catalyst in CO2 hydrogenation to methanol SCIE
期刊论文 | 2024 , 436 | CATALYSIS TODAY
Abstract&Keyword Cite

Abstract :

The escalating emission of CO2 has caused a significant environmental impact. Hydrogenation of CO2 to methanol stands as the primary objective in the liquid sunlight vision, aiming to mitigate CO2 emissions. CuZn-based transition metal catalysts, known for their cost-effectiveness, demonstrate commendable catalytic performance at moderate temperatures and pressures, showcasing considerable potential in industrial applications. Consequently, a series of catalysts, composed of CuZn-based species supported on CeO2 with strategically introduced appropriate oxygen vacancies, were meticulously prepared. It worth to noting that the size of Cu was precisely tuned, along with the enhanced ability to the adsorption and activation of CO2 and H-2. As a result, the optimal CuZn/CeO2 catalyst exhibits high methanol formation rate, recording at 433.4 g(MeOH) kg(cat)(-1) h(-1) with selectivity of 68.5% at 260 degrees C and 3 MPa. Simultaneously, the reaction path and the evolution of intermediates in CO2 hydrogenation was thoroughly delineated.

Keyword :

Oxygen vacancy Oxygen vacancy CH3OH selectivity CH3OH selectivity CO2 hydrogenation CO2 hydrogenation Copper size effect Copper size effect

Cite:

Copy from the list or Export to your reference management。

GB/T 7714 Zhang, Lan , Hu, Xiaomin , Wang, Ning et al. The copper size effect of CuZn/CeO2 catalyst in CO2 hydrogenation to methanol [J]. | CATALYSIS TODAY , 2024 , 436 .
MLA Zhang, Lan et al. "The copper size effect of CuZn/CeO2 catalyst in CO2 hydrogenation to methanol" . | CATALYSIS TODAY 436 (2024) .
APA Zhang, Lan , Hu, Xiaomin , Wang, Ning , Chen, Biaohua . The copper size effect of CuZn/CeO2 catalyst in CO2 hydrogenation to methanol . | CATALYSIS TODAY , 2024 , 436 .
Export to NoteExpress RIS BibTex
MoS 2 supported Ruthenium nanoparticles with abundant sulfur vacancies significantly improved hydrogen evolution reaction SCIE
期刊论文 | 2024 , 436 | CATALYSIS TODAY
Abstract&Keyword Cite

Abstract :

The electrochemical hydrogen evolution reaction (HER) has become one of effective ways to produce hydrogen. MoS2 is a promising electrocatalyst for the HER, and loading noble metal atoms on MoS2 support can further enhance its HER activity. In present work, the CO was employed as a structure-directing agent to in situ synthesize MoS2-n (n = 0, 0.5, 1.0, 1.4 and 2.0 MPa, representing the CO pressure). Among them, the MoS2-1.4 with highest amounts of sulfur vacancies and superior alkaline HER performance was selected as the support for Ru loadings. Sulfur vacancies can stabilize Ru nanoparticles, prevent nanoparticles from aggregating, and facilitate the formation of small-sized nanoparticles. By optimizing the loading amounts of Ru, the 5Ru@MoS2-1.4 with the Ru loading of 5 wt.% and nanoparticle size of 2 nm exhibits the best alkaline HER activity by displaying a low overpotential of 55 mV and Tafel slope of 68.6 mV dec- 1 at a current density of 10 mA cm-2 in 1.0 M KOH medium. This can be majorly related to the synergistic effect of MoS2-1.4 support and small-sized Ru nanoparticles, wherein the CO plays a significant role in regulating the structure of MoS2-1.4 support that favors dispersion of Ru nanoparticles. Generally, present work provides a strategy to enhance the HER catalytic performance of MoS2, which is favorable for other highly-efficient catalyst design.

Keyword :

Hydrogen evolution reaction Hydrogen evolution reaction Ru nanoparticles Ru nanoparticles CO structure-directing agent CO structure-directing agent Sulfur vacancies Sulfur vacancies MoS2 MoS2

Cite:

Copy from the list or Export to your reference management。

GB/T 7714 Liu, Lei , Liu, Ning , Dai, Chengna et al. MoS 2 supported Ruthenium nanoparticles with abundant sulfur vacancies significantly improved hydrogen evolution reaction [J]. | CATALYSIS TODAY , 2024 , 436 .
MLA Liu, Lei et al. "MoS 2 supported Ruthenium nanoparticles with abundant sulfur vacancies significantly improved hydrogen evolution reaction" . | CATALYSIS TODAY 436 (2024) .
APA Liu, Lei , Liu, Ning , Dai, Chengna , Xu, Ruinian , Yu, Gangqiang , Wang, Ning et al. MoS 2 supported Ruthenium nanoparticles with abundant sulfur vacancies significantly improved hydrogen evolution reaction . | CATALYSIS TODAY , 2024 , 436 .
Export to NoteExpress RIS BibTex
一种使用离子液体/磷酸三辛酯从高镁锂比盐湖卤水中分离锂镁的协同溶剂萃取方法 incoPat
专利 | 2023-04-28 | CN202310475637.5
Abstract&Keyword Cite

Abstract :

本发明开发了一种使用离子液体/磷酸三辛酯从高镁锂比盐湖卤水中分离锂镁的协同溶剂萃取方法。该方法以磷酸三辛酯为萃取剂、离子液体1‑(2‑羟基乙基)‑3‑甲基咪唑双(三氟甲磺酰基)亚胺([HOEMIM][Tf2N])为协同萃取剂、(水)为反萃剂组成萃取体系,在有机相与水相体积比0.5:1 5:1,单次萃取时间15 60min, 萃取温度20 35℃,经过萃取、反萃和深度除镁后制备碳酸锂。本发明具备如下优势:一是该萃取体系在中性卤水中锂萃取率较高,同时锂镁分离系数较大,能够达到较好的锂镁分离效果,无需加酸碱调控pH值;二是萃取过程无乳化现象及第三相出现;三是离子液体作为绿色溶剂,具有高稳定性、不可燃性、几乎不挥发等特点,绿色环保。

Cite:

Copy from the list or Export to your reference management。

GB/T 7714 刘宁 , 张薪和 , 于刚强 et al. 一种使用离子液体/磷酸三辛酯从高镁锂比盐湖卤水中分离锂镁的协同溶剂萃取方法 : CN202310475637.5[P]. | 2023-04-28 .
MLA 刘宁 et al. "一种使用离子液体/磷酸三辛酯从高镁锂比盐湖卤水中分离锂镁的协同溶剂萃取方法" : CN202310475637.5. | 2023-04-28 .
APA 刘宁 , 张薪和 , 于刚强 , 代成娜 , 陈标华 , 徐瑞年 et al. 一种使用离子液体/磷酸三辛酯从高镁锂比盐湖卤水中分离锂镁的协同溶剂萃取方法 : CN202310475637.5. | 2023-04-28 .
Export to NoteExpress RIS BibTex
一种H2分子原位调控Pt/M-CeO2催化剂的制备方法及其在制烯烃中的应用 incoPat
专利 | 2023-01-19 | CN202310097577.8
Abstract&Keyword Cite

Abstract :

本发明公开了一种H2分子原位调控Pt/M‑CeO2催化剂的制备方法及其在制烯烃中的应用。本发明在100ml四氟内衬中加入6mol/L的NaOH溶液及铈源,按照Pt : M质量比为1 : 3,加入铂源以及一定量的金属源(Sn, Fe, Cu,Co, Zn)形成悬浮液,搅拌30min后原位通入1MPa H2,于100℃晶化24小时,制得系列Pt/M‑CeO2催化剂,本发明合成方法简便,可制备低Pt负载量的催化材料,大大降低了成本,且具有大量的活性位点, 在一定程度上提高了催化活性。本发明制得的Pt/M‑CeO2催化剂应用于CO2氧化丙烷制烯烃过程中,表现出优异的催化性能,具有很高的应用价值。

Cite:

Copy from the list or Export to your reference management。

GB/T 7714 刘宁 , 牛宇琪 , 代成娜 et al. 一种H2分子原位调控Pt/M-CeO2催化剂的制备方法及其在制烯烃中的应用 : CN202310097577.8[P]. | 2023-01-19 .
MLA 刘宁 et al. "一种H2分子原位调控Pt/M-CeO2催化剂的制备方法及其在制烯烃中的应用" : CN202310097577.8. | 2023-01-19 .
APA 刘宁 , 牛宇琪 , 代成娜 , 陈标华 . 一种H2分子原位调控Pt/M-CeO2催化剂的制备方法及其在制烯烃中的应用 : CN202310097577.8. | 2023-01-19 .
Export to NoteExpress RIS BibTex
一种加氢脱硫催化剂及其制备方法和应用 incoPat
专利 | 2023-03-24 | CN202310296350.6
Abstract&Keyword Cite

Abstract :

本发明涉及一种加氢脱硫催化剂及其制备方法和应用,利用气体小分子CO作为结构导向剂,使现有技术中的Co‑MoS2催化剂由传统的球形结构变为比表面积更大,活性位点更多的非球形结构,所述1T相MoS2在催化剂中的摩尔占比为62.6‑77.6%,所述催化剂中的MoS2为二维层状材料,每层均由MoS2组成,层与层之间的距离为层间距,所述层间距的范围为Co元素均匀分布在MoS2中,所述催化剂比表面积为65.9‑142.4m2/g,所述催化剂的活性位点在催化剂中的摩尔占比为62.3‑63.9%,1T相的高占比、MoS2的高层间距及高活性位点相互结合,共同提升所述催化剂加氢脱硫的性能。

Cite:

Copy from the list or Export to your reference management。

GB/T 7714 陈标华 , 刘磊 , 刘宁 et al. 一种加氢脱硫催化剂及其制备方法和应用 : CN202310296350.6[P]. | 2023-03-24 .
MLA 陈标华 et al. "一种加氢脱硫催化剂及其制备方法和应用" : CN202310296350.6. | 2023-03-24 .
APA 陈标华 , 刘磊 , 刘宁 , 代成娜 . 一种加氢脱硫催化剂及其制备方法和应用 : CN202310296350.6. | 2023-03-24 .
Export to NoteExpress RIS BibTex
一种己二酸尾气中N2O的资源化利用方法 incoPat
专利 | 2023-05-26 | CN202310610004.0
Abstract&Keyword Cite

Abstract :

本发明涉及一种己二酸尾气中N2O的资源化利用方法,在不使用催化剂的条件下,仍可以将已二酸尾气中的N2O进行处理,并且能进一步生产出具有工业价值的硝酸和不会对环境造成影响的氮气与氧气,在达到对己二酸尾气中N2O进行处理的同时产生经济效益,且工艺简单、N2O脱除率高、稳定性高、环境友好和资源化利用率高,还能大幅度降低尾气催化处理的成本。并且本发明的方法能够连续运转,能够持续解决己二酸工业尾气排放问题,使其达到工业排放标准,降低企业处理尾气的成本,具有重要的现实意义和工程应用价值。

Cite:

Copy from the list or Export to your reference management。

GB/T 7714 陈标华 , 潘磊 , 徐瑞年 . 一种己二酸尾气中N2O的资源化利用方法 : CN202310610004.0[P]. | 2023-05-26 .
MLA 陈标华 et al. "一种己二酸尾气中N2O的资源化利用方法" : CN202310610004.0. | 2023-05-26 .
APA 陈标华 , 潘磊 , 徐瑞年 . 一种己二酸尾气中N2O的资源化利用方法 : CN202310610004.0. | 2023-05-26 .
Export to NoteExpress RIS BibTex
Aromatic volatile organic compounds absorption with phenyl-based deep eutectic solvents: A molecular thermodynamics and dynamics study SCIE
期刊论文 | 2023 , 69 (5) | AICHE JOURNAL
Abstract&Keyword Cite

Abstract :

The suitability of phenyl-based deep eutectic solvents (DESs) as absorbents for toluene absorption was investigated by means of thermodynamic modeling and molecular dynamics (MD). The thermodynamic models perturbed-chain statistical associating fluid theory (PC-SAFT) and conductor-like screening model for real solvents (COSMO-RS) were used to predict the vapor-liquid equilibrium of DES-toluene systems. PC-SAFT yielded quantitative results even without using any binary fitting parameters. Among the five DESs studied in this work, [TEBAC][PhOH] consisting of triethyl benzyl ammonium chloride (TEBAC) and phenol (PhOH), was considered as the most suitable absorbent. Systems with [TEBAC][PhOH] had lowest equilibrium pressures of the considered DES-toluene mixtures, the best thermodynamic characteristics (i.e., Henry's law constant, excess enthalpy, Gibbs free energy of solvation of toluene), and the highest self-diffusion coefficient of toluene. The molecular-level mechanism was explored by MD simulations, indicating that [TEBAC][PhOH] has the strongest interaction of DES-toluene compared to the other DESs under study. This work provides guidance to rationally design novel DESs for efficient aromatic volatile organic compounds absorption.

Keyword :

COSMO-RS model COSMO-RS model molecular dynamics simulation molecular dynamics simulation PC-SAFT model PC-SAFT model deep eutectic solvent deep eutectic solvent VOC absorption VOC absorption

Cite:

Copy from the list or Export to your reference management。

GB/T 7714 Yu, Gangqiang , Gajardo-Parra, Nicolas F. , Chen, Min et al. Aromatic volatile organic compounds absorption with phenyl-based deep eutectic solvents: A molecular thermodynamics and dynamics study [J]. | AICHE JOURNAL , 2023 , 69 (5) .
MLA Yu, Gangqiang et al. "Aromatic volatile organic compounds absorption with phenyl-based deep eutectic solvents: A molecular thermodynamics and dynamics study" . | AICHE JOURNAL 69 . 5 (2023) .
APA Yu, Gangqiang , Gajardo-Parra, Nicolas F. , Chen, Min , Chen, Biaohua , Sadowski, Gabriele , Held, Christoph . Aromatic volatile organic compounds absorption with phenyl-based deep eutectic solvents: A molecular thermodynamics and dynamics study . | AICHE JOURNAL , 2023 , 69 (5) .
Export to NoteExpress RIS BibTex
10| 20| 50 per page
< Page ,Total 8 >

Export

Results:

Selected

to

Format:
Online/Total:221/5771181
Address:BJUT Library(100 Pingleyuan,Chaoyang District,Beijing 100124, China Post Code:100124) Contact Us:010-67392185
Copyright:BJUT Library Technical Support:Beijing Aegean Software Co., Ltd.