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Cuboid-like phosphorus-doped metal-organic framework-derived CoSe2 on carbon cloth as an advanced bifunctional oxygen electrocatalyst for rechargeable zinc-air batteries SCIE
期刊论文 | 2023 , 633 , 424-431 | JOURNAL OF COLLOID AND INTERFACE SCIENCE
WoS核心集被引次数: 11
摘要&关键词 引用

摘要 :

Zinc-air batteries (ZABs) are regarded as attractive devices for electrochemical energy storage and conversion due to their outstanding electrochemical performance, low price, and high safety. However, it remains a chal-lenge to design a stable and efficient bifunctional oxygen catalyst that can accelerate the reaction kinetics and improve the performance of ZABs. Herein, a phosphorus-doped transition metal selenide/carbon com-posite catalyst derived from metal-organic frameworks (P-CoSe2/C@CC) is constructed by a self-supporting carbon cloth structure through a simple solvothermal process with subsequent selenization and phosphati-zation. The P-CoSe2/C@CC exhibits a low overpotential of 303.1 mV at 10 mA cm-2 toward the oxygen evo-lution reaction and an obvious reduction peak for the oxygen reduction reaction. The abovementioned electrochemical performances for the P-CoSe2/C@CC are attributed to the specific architecture, the super-hydrophilic surface, and the P-doping effect. Remarkably, the homemade zinc-air battery based on our P-CoSe2/C@CC catalyst shows an expected peak power density of 124.4 mW cm-2 along with excellent cycling stability, confirming its great potential application in ZABs for advanced bifunctional electrocatalysis.(c) 2022 Elsevier Inc. All rights reserved.

关键词 :

Zinc-air battery Zinc-air battery Phosphorus doping Phosphorus doping Bifunctional oxygen catalyst Bifunctional oxygen catalyst Metal-organic frameworks Metal-organic frameworks Cobalt selenide Cobalt selenide

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GB/T 7714 Mi, Hongtian , Li, Leyuan , Zeng, Chuitao et al. Cuboid-like phosphorus-doped metal-organic framework-derived CoSe2 on carbon cloth as an advanced bifunctional oxygen electrocatalyst for rechargeable zinc-air batteries [J]. | JOURNAL OF COLLOID AND INTERFACE SCIENCE , 2023 , 633 : 424-431 .
MLA Mi, Hongtian et al. "Cuboid-like phosphorus-doped metal-organic framework-derived CoSe2 on carbon cloth as an advanced bifunctional oxygen electrocatalyst for rechargeable zinc-air batteries" . | JOURNAL OF COLLOID AND INTERFACE SCIENCE 633 (2023) : 424-431 .
APA Mi, Hongtian , Li, Leyuan , Zeng, Chuitao , Jin, Yuhong , Zhang, Qianqian , Zhou, Kailing et al. Cuboid-like phosphorus-doped metal-organic framework-derived CoSe2 on carbon cloth as an advanced bifunctional oxygen electrocatalyst for rechargeable zinc-air batteries . | JOURNAL OF COLLOID AND INTERFACE SCIENCE , 2023 , 633 , 424-431 .
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Porous hierarchical Ni2P nanosheet arrays combined with Cu3P layers on copper foam as a binder-free battery-type cathode for high-energy-density asymmetrical all-solid-state electrochemical capacitors SCIE
期刊论文 | 2022 , 52 | JOURNAL OF ENERGY STORAGE
WoS核心集被引次数: 4
摘要&关键词 引用

摘要 :

Transition metal phosphides with a satisfying theoretical electrochemical characteristics are the promising environmentally friendly energy storage materials for high-performance electrochemical capacitors. The possession of high specific surface area, numerous active sites and stable structure is helpful for the electrochemical energy storage process. In this study, porous hierarchical Ni2P nanosheet arrays combined with Cu3P layers on copper foam (Ni2P/C@Cu3P-CF) is fabricated via hydrothermal-reduction/carbonization-phosphorization process using the 2D Ni-based metal organic framework nanosheets as the precursor. Benefit from this rational design and super-hydrophilic property, the Ni2P/C@Cu3P-CF electrode possess a satisfying capacity of 1105.0 mC cm(-2) at a current density of 5 mA cm(-2) and good rate performance (61.5% capacity retention at a high current density of 50 mA cm(-2)). In addition, asymmetrical all-solid-state electrochemical capacitors assembled with our Ni2P/C@Cu3P-CF electrode can deliver a high areal energy density of 1.6 mWh cm(-2 )at a power density of 0.16 mW cm(-2). Moreover, this electrochemical capacitors display the robust cycling stability with a 91.2% capacity retention after 5000 cycles at a rate of 10 mA cm(-2). These results demonstrate a great potential for the Ni2P/C@Cu3P-CF electrode in the commercial application of the advanced aqueous electrochemical energy storage device.

关键词 :

Asymmetrical electrochemical capacitors Asymmetrical electrochemical capacitors Cu 3 P layer Cu 3 P layer Ni2P nanosheet Ni2P nanosheet Ni-MOF Ni-MOF High areal capacitance High areal capacitance

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GB/T 7714 Li, Leyuan , Jin, Yuhong , Zeng, Chuitao et al. Porous hierarchical Ni2P nanosheet arrays combined with Cu3P layers on copper foam as a binder-free battery-type cathode for high-energy-density asymmetrical all-solid-state electrochemical capacitors [J]. | JOURNAL OF ENERGY STORAGE , 2022 , 52 .
MLA Li, Leyuan et al. "Porous hierarchical Ni2P nanosheet arrays combined with Cu3P layers on copper foam as a binder-free battery-type cathode for high-energy-density asymmetrical all-solid-state electrochemical capacitors" . | JOURNAL OF ENERGY STORAGE 52 (2022) .
APA Li, Leyuan , Jin, Yuhong , Zeng, Chuitao , Ren, Dayong , Zhou, Kailing , Zhang, Qianqian et al. Porous hierarchical Ni2P nanosheet arrays combined with Cu3P layers on copper foam as a binder-free battery-type cathode for high-energy-density asymmetrical all-solid-state electrochemical capacitors . | JOURNAL OF ENERGY STORAGE , 2022 , 52 .
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An aqueous aluminum-ion electrochromic energy storage device with visual energy level SCIE
期刊论文 | 2022 , 248 | SOLAR ENERGY MATERIALS AND SOLAR CELLS
WoS核心集被引次数: 17
摘要&关键词 引用

摘要 :

Electrochromic energy storage devices (EESDs) integrate energy storage and electrochromism into one smart device that can realize the visualization of the energy level by the naked eyes, which has attracted extensive attention in recent years. It is critical to explore suitable electrode materials for achieving both high electrochromic and electrochemical performance. Herein, we propose an aqueous aluminum-ion electrochromic energy storage device (AIEESD) by assembling the polyaniline (PANI) electrochromic cathode, Al metal frame anode and AlCl3 electrolyte, which yields an open-circuit voltage of similar to 1.22 V and a fast self-bleaching behavior without any energy input. Additionally, the developed device exhibits outstanding electrochromic energy storage performances with discharging capacity of 68.1 mAh m(-2), excellent rate capability, large optical modulation (Delta T = 55% at 630 nm) and high coloration efficiency (93.62 cm(2) C-1 at 630 nm). Moreover, the prototype device can reversibly switch between the multicolor (transparent, light yellow, green and dark blue) when the voltage changes from 0.4 to 2.5 V, which means the energy status can be monitored by the obvious color transition. These results show that the AIEESD in this work has great application prospects for smart windows and energy storage displays.

关键词 :

Electrochromic Electrochromic Energy storage Energy storage Polyaniline Polyaniline Self-bleaching Self-bleaching

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GB/T 7714 Gong, Hui , Wang, Shuyi , Xie, Ming et al. An aqueous aluminum-ion electrochromic energy storage device with visual energy level [J]. | SOLAR ENERGY MATERIALS AND SOLAR CELLS , 2022 , 248 .
MLA Gong, Hui et al. "An aqueous aluminum-ion electrochromic energy storage device with visual energy level" . | SOLAR ENERGY MATERIALS AND SOLAR CELLS 248 (2022) .
APA Gong, Hui , Wang, Shuyi , Xie, Ming , Wang, Hao . An aqueous aluminum-ion electrochromic energy storage device with visual energy level . | SOLAR ENERGY MATERIALS AND SOLAR CELLS , 2022 , 248 .
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Design strategies toward transition metal selenide-based catalysts for electrochemical water splitting SCIE
期刊论文 | 2021 , 5 (5) , 1347-1365 | SUSTAINABLE ENERGY & FUELS
WoS核心集被引次数: 43
摘要&关键词 引用

摘要 :

Electrochemical water splitting is the most direct and popular method to obtain hydrogen. However, the high activation barrier for water splitting greatly hinders large-scale hydrogen production, inspiring the necessity of using catalysts for the hydrogen evolution reaction and oxygen evolution reaction. Materials from precious metals to earth-abundant transition metals and their composites have been widely developed, in which transition metal selenides display a more outstanding bifunctional catalytic performance. This review aims to focus on the design strategies of transition metal selenide based catalysts from modification methods, including morphological control, anion substitution and cation substitution, as well as using composite materials modified by constructing heterostructures and the synergistic effect of different components. Finally, it provides guidance for the research status, and future development directions of multifunctional electrocatalytic selenide based materials are also suggested.

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GB/T 7714 Zeng, ChuiTao , Dai, Lingyun , Jin, YuHong et al. Design strategies toward transition metal selenide-based catalysts for electrochemical water splitting [J]. | SUSTAINABLE ENERGY & FUELS , 2021 , 5 (5) : 1347-1365 .
MLA Zeng, ChuiTao et al. "Design strategies toward transition metal selenide-based catalysts for electrochemical water splitting" . | SUSTAINABLE ENERGY & FUELS 5 . 5 (2021) : 1347-1365 .
APA Zeng, ChuiTao , Dai, Lingyun , Jin, YuHong , Liu, JingBing , Zhang, QianQian , Wang, Hao . Design strategies toward transition metal selenide-based catalysts for electrochemical water splitting . | SUSTAINABLE ENERGY & FUELS , 2021 , 5 (5) , 1347-1365 .
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Recent advances in understanding and relieving capacity decay of lithium ion batteries with layered ternary cathodes SCIE
期刊论文 | 2021 , 5 (20) , 5114-5138 | SUSTAINABLE ENERGY & FUELS
WoS核心集被引次数: 21
摘要&关键词 引用

摘要 :

Layered ternary lithium-ion batteries LiNixCoyMnzO2 (NCM) and LiNixCoyAlzO2 (NCA) have become mainstream power batteries due to their large specific capacity, low cost, and high energy density. However, these layered ternary lithium-ion batteries still have electrochemical cycling problems such as rapid capacity decline and poor thermal stability. These problems are mainly caused by (1) irreversible phase transition, (2) crack and pulverization of cathode electrode material particles, (3) dissolution of transition metal elements, (4) oxidative decomposition of electrolyte and (5) repeated growth and thickening of the SEI film on the anode electrode. In order to solve these problems, various strategies based on doping and coating of the cathode material, design of electrolyte, and anode coating have been studied to effectively stabilize the NCM/NCA cathode and achieve the purpose of improving its electrochemical cycling performance. This review briefly describes the working principle of lithium-ion batteries, the composition and structure of NCM/NCA cathode materials and the roles of transition metal elements. The capacity degradation mechanism of layered ternary lithium-ion batteries is reviewed from the perspectives of cathode, electrolyte and anode, and the research progress in the modification of cathode materials is emphatically discussed. Advances in the modification of anode materials and electrolyte design are also briefly introduced. Finally, some challenges and prospects are proposed for the future development of layered ternary lithium-ion batteries.

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GB/T 7714 Zhang, JianHua , Jin, YuHong , Liu, JingBing et al. Recent advances in understanding and relieving capacity decay of lithium ion batteries with layered ternary cathodes [J]. | SUSTAINABLE ENERGY & FUELS , 2021 , 5 (20) : 5114-5138 .
MLA Zhang, JianHua et al. "Recent advances in understanding and relieving capacity decay of lithium ion batteries with layered ternary cathodes" . | SUSTAINABLE ENERGY & FUELS 5 . 20 (2021) : 5114-5138 .
APA Zhang, JianHua , Jin, YuHong , Liu, JingBing , Zhang, QianQian , Wang, Hao . Recent advances in understanding and relieving capacity decay of lithium ion batteries with layered ternary cathodes . | SUSTAINABLE ENERGY & FUELS , 2021 , 5 (20) , 5114-5138 .
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Direct fabrication of electrochromic Ni-MOF 74 film on ITO with high-stable performance SCIE
期刊论文 | 2021 , 27 (8) , 3655-3662 | IONICS
WoS核心集被引次数: 12
摘要&关键词 引用

摘要 :

Metal-organic framework (MOF) is a promising electrochromic material due to its high specific surface area and tunable pore size, which can benefit the fast transportation of ion/charge. Here, a simple solvothermal deposition method for fabrication of Ni-MOF 74 electrochromic films on ITO is developed. It is found that the reaction temperature has played an important role in the morphology and electrochromic performance of as-prepared Ni-MOF 74 film. The film prepared at the optimized temperature exhibits the best electrochromic performance with a rapid switching speed (the coloration/bleaching time = 24.5/23.5 s). In addition, the optimized film displays a high optical contrast of 44.4% at 550 nm and can be stably switched for 650 cycles with < 21.5% contrast attenuation. The electrochromism of Ni-MOF 74 can be attributed to the oxidized and reduced states of 2,5-dihydroxyterephthalic acid ligands. This simple method can be broaden to fabricate other metal-based MOF films for electrochromic applications.

关键词 :

Electrochromic materials Electrochromic materials ITO substrate ITO substrate Ni-MOF 74 Ni-MOF 74 Thin film Thin film

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GB/T 7714 Zhang, Ning , Jin, Yuhong , Zhang, Qianqian et al. Direct fabrication of electrochromic Ni-MOF 74 film on ITO with high-stable performance [J]. | IONICS , 2021 , 27 (8) : 3655-3662 .
MLA Zhang, Ning et al. "Direct fabrication of electrochromic Ni-MOF 74 film on ITO with high-stable performance" . | IONICS 27 . 8 (2021) : 3655-3662 .
APA Zhang, Ning , Jin, Yuhong , Zhang, Qianqian , Liu, Jingbing , Zhang, Yongzhe , Wang, Hao . Direct fabrication of electrochromic Ni-MOF 74 film on ITO with high-stable performance . | IONICS , 2021 , 27 (8) , 3655-3662 .
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Fabrication of Vertical-Standing Co-MOF Nanoarrays with 2D Parallelogram-like Morphology for Aqueous Asymmetric Electrochemical Capacitors SCIE
期刊论文 | 2021 , 26 (17) | MOLECULES
WoS核心集被引次数: 9
摘要&关键词 引用

摘要 :

Metal organic frameworks (MOFs) have been considered as one of the most promising electrode materials for electrochemical capacitors due to their large specific surface area and abundant pore structure. Herein, we report a Co-MOF electrode with a vertical-standing 2D parallelogram-like nanoarray structure on a Ni foam substrate via a one-step solvothermal method. The as-prepared Co-MOF on a Ni foam electrode delivered a high area-specific capacitance of 582.0 mC cm(-2) at a current density of 2 mA cm(-2) and a good performance rate of 350.0 mC cm(-2) at 50 mA cm(-2). Moreover, an asymmetric electrochemical capacitor (AEC) device (Co-MOF on Ni foam//AC) was assembled by using the as-prepared Co-MOF on a Ni foam as the cathode and a active carbon-coated Ni foam as the anode to achieve a maximum energy density of 0.082 mW cm(-2) at a power density of 0.8 mW cm(-2), which still maintained 0.065 mW cm(-2) at a high power density of 11.94 mW cm(-2). Meanwhile, our assembled device exhibited an excellent cycling stability with a capacitance retention of nearly 100% after 1000 cycles. Therefore, this work provides a simple method to prepare MOF-based material for the application of energy storage and conversion.

关键词 :

asymmetric electrochemical capacitors asymmetric electrochemical capacitors Co-MOF Co-MOF metal organic frameworks metal organic frameworks nanoarrays nanoarrays

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GB/T 7714 Li, Leyuan , Mi, Hongtian , Jin, Yuhong et al. Fabrication of Vertical-Standing Co-MOF Nanoarrays with 2D Parallelogram-like Morphology for Aqueous Asymmetric Electrochemical Capacitors [J]. | MOLECULES , 2021 , 26 (17) .
MLA Li, Leyuan et al. "Fabrication of Vertical-Standing Co-MOF Nanoarrays with 2D Parallelogram-like Morphology for Aqueous Asymmetric Electrochemical Capacitors" . | MOLECULES 26 . 17 (2021) .
APA Li, Leyuan , Mi, Hongtian , Jin, Yuhong , Ren, Dayong , Zhou, Kailing , Zhang, Qianqian et al. Fabrication of Vertical-Standing Co-MOF Nanoarrays with 2D Parallelogram-like Morphology for Aqueous Asymmetric Electrochemical Capacitors . | MOLECULES , 2021 , 26 (17) .
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High-Precision Temperature Inversion Algorithm for Correlative Microwave Radiometer SCIE
期刊论文 | 2021 , 21 (16) | SENSORS
WoS核心集被引次数: 4
摘要&关键词 引用

摘要 :

In order to achieve high precision from non-contact temperature measurement, the hardware structure of a broadband correlative microwave radiometer, calibration algorithm, and temperature inversion algorithm are innovatively designed in this paper. The correlative radiometer is much more sensitive than a full power radiometer, but its accuracy is challenging to improve due to relatively large phase error. In this study, an error correction algorithm is designed, which reduces the phase error from 69.08 degrees to 4.02 degrees. Based on integral calibration on the microwave temperature measuring system with a known radiation source, the linear relationship between the output voltage and the brightness temperature of the object is obtained. Since the metal aluminum plate, antenna, and transmission line will have a non-linear influence on the receiver system, their temperature characteristics and the brightness temperature of the object are used as the inputs of the neural network to obtain a higher accuracy of inversion temperature. The temperature prediction mean square error of a back propagation (BP) neural network is 0.629 degrees C, and its maximum error is 3.351 degrees C. This paper innovatively proposed the high-precision PSO-LM-BP temperature inversion algorithm. According to the global search ability of the particle swarm optimization (PSO) algorithm, the initial weight of the network can be determined effectively, and the Levenberg-Marquardt (LM) algorithm makes use of the second derivative information, which has higher convergence accuracy and iteration efficiency. The mean square error of the PSO-LM-BP temperature inversion algorithm is 0.002 degrees C, and its maximum error is 0.209 degrees C.

关键词 :

correction algorithm correction algorithm integral calibration integral calibration correlative radiometer correlative radiometer PSO-LM-BP inversion algorithm PSO-LM-BP inversion algorithm

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GB/T 7714 Liu, Jie , Zhang, Kai , Ma, Jingyan et al. High-Precision Temperature Inversion Algorithm for Correlative Microwave Radiometer [J]. | SENSORS , 2021 , 21 (16) .
MLA Liu, Jie et al. "High-Precision Temperature Inversion Algorithm for Correlative Microwave Radiometer" . | SENSORS 21 . 16 (2021) .
APA Liu, Jie , Zhang, Kai , Ma, Jingyan , Wu, Qiang , Sun, Zhenlin , Wang, Hao et al. High-Precision Temperature Inversion Algorithm for Correlative Microwave Radiometer . | SENSORS , 2021 , 21 (16) .
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Two-dimensional materials towards separator functionalization in advanced Li-S batteries SCIE
期刊论文 | 2021 , 13 (45) , 18883-18911 | NANOSCALE
WoS核心集被引次数: 15
摘要&关键词 引用

摘要 :

Functional separators have played important roles in improving the electrochemical performance of lithium-sulfur (Li-S) batteries by addressing the key issues of both the sulfur cathode and lithium anode. Compared with other materials that are used for separator functionalization, two-dimensional (2D) materials with atomic layer thickness and infinite lateral dimensions feature several advantages of ultra-thin laminate structure, remarkable physical properties and tunable surface chemistry, which show potential applications in separator functionalization towards addressing the issues of both the shuttle effect and formation of Li dendrites in Li-S batteries. In this review, the unique advantages of 2D materials for separator functionalization in Li-S batteries and their common construction methods are introduced. Then, recent progress and advances in the construction of 2D materials functional separators are summarized in detail towards inhibiting the shuttle effect of polysulfides and suppressing Li dendrite growth in Li-S batteries. Finally, some opportunities and challenges of 2D materials for constructing high-performance functional separators are proposed. We anticipate that this review will provide new insights into separator functionalization for developing advanced Li-S batteries.

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GB/T 7714 Tang, Jiadong , Zhao, Qing , Li, Fenglei et al. Two-dimensional materials towards separator functionalization in advanced Li-S batteries [J]. | NANOSCALE , 2021 , 13 (45) : 18883-18911 .
MLA Tang, Jiadong et al. "Two-dimensional materials towards separator functionalization in advanced Li-S batteries" . | NANOSCALE 13 . 45 (2021) : 18883-18911 .
APA Tang, Jiadong , Zhao, Qing , Li, Fenglei , Hao, Zhendong , Xu, Xiaolong , Zhang, Qianqian et al. Two-dimensional materials towards separator functionalization in advanced Li-S batteries . | NANOSCALE , 2021 , 13 (45) , 18883-18911 .
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Atomically Dispersed Platinum Modulated by Sulfide as an Efficient Electrocatalyst for Hydrogen Evolution Reaction SCIE
期刊论文 | 2021 , 8 (12) | ADVANCED SCIENCE
WoS核心集被引次数: 60
摘要&关键词 引用

摘要 :

Catalytically active metals atomically dispersed on supports presents the ultimate atom utilization efficiency and cost-effective pathway for electrocatalyst design. Optimizing the coordination nature of metal atoms represents the advanced strategy for enhancing the catalytic activity and the selectivity of single-atom catalysts (SACs). Here, we designed a transition-metal based sulfide-Ni3S2 with abundant exposed Ni vacancies created by the interaction between chloride ions and the functional groups on the surface of Ni3S2 for the anchoring of atomically dispersed Pt (Pt-SA-Ni3S2). The theoretical calculation reveals that unique Pt-Ni3S2 support interaction increases the d orbital electron occupation at the Fermi level and leads to a shift-down of the d -band center, which energetically enhances H2O adsorption and provides the optimum H binding sites. Introducing Pt into Ni position in Ni3S2 system can efficiently enhance electronic field distribution and construct a metallic-state feature on the Pt sites by the orbital hybridization between S-3p and Pt-5d for improved reaction kinetics. Finally, the fabricated Pt-SA-Ni3S2 SAC is supported by Ag nanowires network to construct a seamless conductive three-dimensional (3D) nanostructure (Pt-SA-Ni3S2@Ag NWs), and the developed catalyst shows an extremely great mass activity of 7.6 A mg(-1) with 27-time higher than the commercial Pt/C HER catalyst.

关键词 :

architectural nanostructure engineering architectural nanostructure engineering atom catalysts (SACs) atom catalysts (SACs) sulfides sulfides support interaction support interaction metal&#8208 metal&#8208 single&#8208 single&#8208 hydrogen evolution reaction (HER) hydrogen evolution reaction (HER)

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GB/T 7714 Zhou, Kai Ling , Han, Chang Bao , Wang, Zelin et al. Atomically Dispersed Platinum Modulated by Sulfide as an Efficient Electrocatalyst for Hydrogen Evolution Reaction [J]. | ADVANCED SCIENCE , 2021 , 8 (12) .
MLA Zhou, Kai Ling et al. "Atomically Dispersed Platinum Modulated by Sulfide as an Efficient Electrocatalyst for Hydrogen Evolution Reaction" . | ADVANCED SCIENCE 8 . 12 (2021) .
APA Zhou, Kai Ling , Han, Chang Bao , Wang, Zelin , Ke, Xiaoxing , Wang, Changhao , Jin, Yuhong et al. Atomically Dispersed Platinum Modulated by Sulfide as an Efficient Electrocatalyst for Hydrogen Evolution Reaction . | ADVANCED SCIENCE , 2021 , 8 (12) .
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